Rails3
Using Postgres
Make sure you have pg gem installed (not the old "postgres" gem)
gem install pg
Making a new app
rails -d postgresql my_rails_app
Your database.yml file
development: adapter: postgresql host: localhost port: 5432 username: your_db_username password: your_db_password database: your_rails_project_development schema_search_path: public encoding: utf8 template: template0
More info
Try this: http://wiki.rubyonrails.org/database-support/postgres